Chemistry of titanium subgroups. Sulfates, fluorides, fluorusufets from water media

The monograph considers phase formation in sulfate-fluoride water systems of the subgroup of titaniums with the distinction between the fields of their existence, the establishment of the chemical composition and characteristics: refractometric, radiometric, thermal and IR spectroscopic. For a number of compounds, a structure with the parameters of an elementary cell is determined and the types of chemical ties are considered. The comparison of all the compounds allocated to date, which made it possible to produce their systematics and predict the possibility of the formation of new compounds related to sulfato, fluoro- and fluorosufatometals of the elements of the titanium subgroup with various external cationic cations.
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